接枝共聚物分子设计及合成方法研究进展  

Research Progress in Molecule Design and Synthetic Technique of Graft Copolymer

作　　者：刘诚[1] 李杨[1] 张春庆[1] 王玉荣[1] 

机构地区：[1]大连理工大学化工学院高分子材料系,大连116012

出　　处：《高分子通报》2009年第5期36-41,共6页Polymer Bulletin

基　　金：国家自然科学基金资助项目(NO.20774015)

摘　　要：接枝共聚物的主链和支链通过分子设计可以被赋予不同性质,从而使得材料拥有两种截然相反的性能。新的接枝合成方法的产生又增加了各种复杂分子结构设计的可实现性。本文围绕接枝共聚物所具有的独特结构和性能特点,详细介绍了近年来接枝共聚物在分子链和星型侧链等方面的研究现状,同时介绍了连接化学,原位氯化接枝共聚等合成方法在接枝共聚合中的应用进展,并展望了接枝共聚物的发展前景。Backbone and branched chain of graft copolymer could be endowed with different properties by molecule design. Consequently, materials were provided with two kinds of properties that were poles apart. New synthetic techniques of graft copolymer increased realizable ability of complex molecule design. Centering on special structure and properties of graft copolymer this review introduced some research productions of graft copolymer on molecule chain and star-tailed side chain design. Furthermore, this review introduced application progress of click chemistry and in situ chlorinating graft copolymerization in synthetic techniques of graft copolymer and made some predictions for the future developments of graft eopolymer.

关 键 词：接枝共聚物 分子设计 合成方法 综述 

分 类 号：O631.3[理学—高分子化学]