微波辐射用于聚酰亚胺的研究进展  

Development of Research on Polyimides by Microwave Irradiation

作　　者：杨小进[1] 陈文求[1] 李全涛[1] 易昌凤[1] 徐祖顺[1] 

机构地区：[1]湖北大学材料科学与工程学院,武汉430062

出　　处：《高分子通报》2009年第5期48-53,共6页Polymer Bulletin

基　　金：湖北省杰出人才基金资助项目(No.2004ABB003)

摘　　要：聚酰亚胺因具有优良的综合性能而得到广泛的研究。微波辐射在高分子化学研究领域中的应用越来越广泛,效果也十分明显。与常规加热方式相比,微波辐射具有内部加热、缩短反应时间、提高反应产率、节省能耗、无温度梯度、制得产物性能好等优点。近年来,微波辐射用于聚酰亚胺的研究越来越多。因此本文对微波辐射在聚酰亚胺的合成、三阶非线性光学、聚酰亚胺复合材料以及稀土-聚酰亚胺配合物等方面的应用进行了综述。Polyimides have been paid much attention, due to their comprehensive properties. Microwave irradiation is widely used in polymerization as a novel and effective way of heating. Microwave irradiation, compared with the traditional heating method, has the advantages of inner heating, shorter reaction time, higher product yield, lower energy consumptions, no temperature gradient, et al. In recent years, applications of microwave irradiation to polyimides have been reported. This paper reviews the application of microwave irradiation to the snythesis of polyimides, third-order nonlinear optical properties, polyimide composite and rare earth metal-polyimide complexes and so on.

关 键 词：聚酰亚胺 微波辐射 聚合反应 

分 类 号：O633.22[理学—高分子化学]