不敏感炸药1-甲基-2,4,5-三硝基咪唑的合成  

Synthesis and characterizeation of 1-methy1-2,4,5-trinitroimidazole

作　　者：宋磊[1] 王小军[1] 李永祥[1] 王建龙[1] 曹端林[1] 

机构地区：[1]中北大学化工与环境学院,山西太原030051

出　　处：《天津化工》2009年第4期20-22,42,共4页Tianjin Chemical Industry

摘　　要：以咪唑为原料,通过两步硝化制得1,4-二硝基咪唑,然后在氯苯中热重排得2,4-二硝基咪唑,将2,4-二硝基咪唑进一步硝化并制得2,4,5-三硝基咪唑的钾盐,最后将钾盐甲基化,得到1-甲基-2,4,5-三硝基咪唑。采用红外光谱、元素分析、核磁的方法对其结构进行表征。用DSC进行了热分解研究。同时优化了2,4-二硝基咪唑的重排工艺:反应温度为120℃～125℃,反应时间为4h,1,4-二硝基咪唑和氯苯的物质的量比为1:30。对2,4,5-三硝基咪唑不稳定性进行了分析。1-methy1-2,4,5-trinitroimidazole （MTNI）is an important polynitro imidazole compoundd.It was synthesized with imidazole as primary substance,by nitrateion obtaining 1,4-dinitroimidazole,and then thermal rearrangement in ehlorobenzene,obtaining 2,4-dinitroimidazole.Natration 2,4-dinitroimidazole and make it become Potassium 2,4,5-trinitroimidazolate.The last,Potassium 2,4,5-trinitroimidazolate was methylated,obtaining 1- methy1-2,4,5-trinitroimidazole.Its structure was characterized by IR elemental analysis and H1NMR.Thermal decomposition of 1-methyl-2,4,5-trinitroimidazole was studied by DSC.Meanwhile,investingating thermal rearrangement, The optimum parameters were as follows;n （1,4-dinitroimidazole）/n （chlorobenzene）=1：30,reaction temperature 120℃-125℃,reaction time 4h. And explain why 2,4,5-trinitroimidazole was unstable.

关 键 词：含能材料 1-甲基-294 5-三硝基咪唑 不敏感炸药 重排工艺 

分 类 号：TB34[一般工业技术—材料科学与工程] TQ560.1[化学工程—炸药化工]