含1,3,3-三硝基氮杂环丁烷(TNAZ)推进剂能量特性计算研究  

Computational investigation of energy characteristics of propellant containing 1,3,3-trinitroazetidine(TNAZ)

作　　者：刘晶如[1] 杨寅 辛伟[3] 

机构地区：[1]江苏工业学院材料科学与工程学院,常州213164 [2]北京理化分析测试中心,北京100089 [3]中国科学院化学研究所,北京100080

出　　处：《固体火箭技术》2009年第3期318-322,共5页Journal of Solid Rocket Technology

摘　　要：利用国军标方法及CAD系统软件,在标准条件(pc/po=70∶1)下,计算了含1,3,3-三硝基氮杂环丁烷(TNAZ)的各类推进剂的能量特性。发现TNAZ单元推进剂的理论比冲为2 700.2 N.s/kg,与DNTF单元推进剂接近;用TNAZ取代丁羟复合固体推进剂中的AP,比冲可提高37.9 N.s/kg;用TNAZ取代NEPE推进剂中的AP,推进剂最大理论比冲可达2 671.1 N.s/kg;NC/NG/TNAZ组成的无烟改性双基推进剂比冲可达2 573.6 N.s/kg;由GAP/TNAZ/RDX组成的无烟推进剂,在很宽的范围内都可得到2 600 N.s/kg以上较高的理论比冲值。研究结果表明,TNAZ在高能推进剂尤其在高能无烟推进剂中有着广阔的应用前景。Under standard condition （pc/po = 70： 1 ）, the energy parameters of the propellant containing 1,3,3-trinitroazetidine （TNAZ） were calculated by GJB/Z 84---96 and CAD system of propellant energy calculation. The theoretical specific impulse of the TNAZ monopropellant is 2 700.2 N · s/kg, which is close to that of the DNTF monopropellant. Replacing ammonium perehlorate with TNAZ in HTPB propellant can increase specific impulse by 37.9 N · s/kg. NEPE propellant has a specific impulse of 2 671.1 N·s/kg when ammonium perchlorate is replaced with TNAZ. NC/NG/TNAZ smokeless MDB propellant has a specific impulse of 2 573.6 N · s/kg. GAP/TNAZ/RDX smokeless propellant has a high value of specific impulse over 2 600 N · s/kg in very wide scope. The results show that TNAZ is a prominent energetic oxidizer in high energy and smokeless propellants.

关 键 词：1 3 3-三硝基氮杂环丁烷(TNAZ) 氧化剂 高能推进剂 无烟推进剂 能量特性 

分 类 号：V512[航空宇航科学与技术—航空宇航推进理论与工程]