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作 者:钟润生[1] 张锡辉[1] 肖峰[2] 李晓岩[2]
机构地区:[1]清华大学深圳研究生院环境工程与管理研究中心,深圳518055 [2]香港大学土木工程系
出 处:《环境科学》2009年第8期2353-2357,共5页Environmental Science
基 金:国家高技术研究发展计划(863)项目(2002AA601120);国家自然科学基金项目(20721140019;U0773002)
摘 要:利用基于微天平的质量-粒径法和基于改进粒子图像测速技术的自由沉淀法对高岭土、腐殖酸絮体的分形结构进行了研究.结果表明,质量-粒径法得到的铁盐絮体三维分形维数为2.14-2.28,明显大于铝盐絮体的1.75-1.83,铁盐絮体结构更为致密,而铝、铁-腐殖酸絮体比相应的高岭土絮体分形维数要小.絮体分形维数与沉淀速度具有良好的对应关系,分形维数越大,絮体沉淀速度越大.质量粒径法与自由沉淀法求出的絮体分形维数相吻合,分形絮体沉淀速度不再满足Stokes沉淀速度公式.Fractal structures of kaolin and humic flcos by the mass-size method based on the microbalance and free-settling method based on particle image velocimetry technique were investigated. The results showed that kaolin and humic flocs were characterized by fractal structure. The three-dimensional fractal dimensions of Fe flocs with more compact structure ranged from 2.14 to 2.28 are larger than those of alum flocs ranged from 1.75 to 1.83 by the mass-size method. The fractal dimensions of humic flocs are smaller than those of kaolin flocs. The fractal dimension has a close relationship with the settling velocity of flocs. The larger the fractal dimension, the higher the settling velocity. The fractal dimensions by the mass-size method are in good agreement with those by the free-settling method. The measured settling velocities of fractal aggregates do not follow with Stokes' law.
关 键 词:絮体结构 沉淀速度 三维分形维数 腐殖酸 粒子图像测速技术
分 类 号:X131.2[环境科学与工程—环境科学]
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