异卟啉研究进展  

A Brief Review of Recent Progress in Porphyrinoids

作　　者：王全国[1] 曾凡花[1] 解永树[1] 朱为宏[1] 

机构地区：[1]华东理工大学结构可控先进功能材料及其制备教育部重点实验室精细化工研究所,上海200237

出　　处：《化学进展》2009年第7期1523-1533,共11页Progress in Chemistry

基　　金：教育部留学回国人员科研启动基金;上海市浦江人才计划(08PJ14037);华东理工大学引进人才启动经费项目资助

摘　　要：异卟啉是通过改变卟啉大环结构而得到的卟啉类似物。由于具有独特的结构和性能,如阴离子识别、稳定异常价态金属离子、Mbius芳香性、构建新型超分子体系、电子转移以及近红外荧光等特性,异卟啉已引起人们越来越多的兴趣。本文简要介绍了异卟啉研究的意义,异卟啉的命名以及分类,并重点介绍了N-错位卟啉、扩展卟啉和氧化卟啉原等异卟啉的研究现状及最新进展。同时对咔咯、氧化咔咯原、卟啉烯、核修饰卟啉、亚卟啉和杯吡咯等异卟啉的发展现状及其性能作了简要概述。通过对异卟啉化合物研究,可得到很多普通卟啉难以实现的性能,并有望在相关领域获得实际应用。本文在介绍异卟啉研究的同时,还尝试翻译了一些相关专业术语。Porphyrinoids are compounds with macrocyclic structures similar attract the attention of chemists due to their unique structures and properties, metal ions with unusual oxidation states, Mobius aromaticity, construction of to those of porphyrins. They continue to such as anion binding, stabilization of interesting supramolecular assemblies,electron transfer, and NIR emission. Significance, nomenclature and classification of porphyrinoids are briefly introduced in this paper. Then recent progress of N-confused porphyrins, expanded porphyrins, and oxoporphyrinogens are highlighted and reviewed. Furthermore, corroles, oxocorrologens, porphycenes, core-modified porphyrins,subporphyrins, calixpyrroles and some other porphyrinoids are also introduced. Researches on porphyrinoids provide the possibilities of interesting properties and relevant applications that might be totally different from normal porphyrin compounds.

关 键 词：异卟啉 N-错位卟啉 扩展卟啉 Mobius芳香性 超分子 阴离子识别 

分 类 号：O626.13[理学—有机化学] O621.3[理学—化学]