合成橡胶常压氢化及产物性能  

Hydrogenation of synthetic rubber under normal pressure and properties of saturated rubber

作　　者：谢洪泉[1,2] 李晓东[1,2] 

机构地区：[1]华中理工大学化学系 [2]湖北省化学研究所

出　　处：《合成橡胶工业》1998年第4期194-197,共4页China Synthetic Rubber Industry

基　　金：中国石化总公司合成橡胶技术开发中心资助

摘　　要：简介了合成橡胶的３种常压氢化方法：（１）用水溶性Ｗｉｌｋｉｎｓｏｎ催化剂在常压氢下使合成胶乳氢化；（２）用对甲苯磺酰肼使合成橡胶在溶液中氢化；（３）用水合肼在氧化剂及铜离子催化剂存在下使合成胶乳在常压下氢化。指出第３种方法最有发展前景，用此方法除了可制备氢化度高的丁腈胶乳外，还可制备具有热塑性弹性体性质的氢化丁苯胶乳及氢化聚丁二烯胶乳；后二者不经硫化即可用于制备耐老化的浸渍制品、涂料、粘接剂、复合垫片等。Three methods for hydrogenation of synthetic rubber or its latex under normal pressure were reviewed with 14 references.Among them the method using hydrazine/H2O2/Cu2+ system for hydrogenation of synthetic rubber latex seemed to be the most prospective.Hydrogenation by this method could not only prepare the saturated nitrile rubber latex,but also obtain the saturated butadiene-styrene rubber latex with thermoplastic elastomer behavior which could be used as antiaging dipping goods,coatings,adhesives and gaskets etc,without vulcanization.

关 键 词：氢化 橡胶 胶乳 热塑性弹性体 合成橡胶 炼胶 

分 类 号：TQ333[化学工程—橡胶工业] TQ330.63