脉冲激光制备发光碳纳米颗粒  

Preparation of Fluorescent Carbon Nanoparticles by Pulsed Laser

作　　者：胡胜亮[1] 白培康[1] 曹士锐[1] 孙景[2] 

机构地区：[1]中北大学材料科学与工程学院,太原030051 [2]天津大学材料科学与工程学院,天津300072

出　　处：《高等学校化学学报》2009年第8期1497-1500,共4页Chemical Journal of Chinese Universities

基　　金：山西省青年科技研究基金(批准号:2009021027);中北大学校青年科技基金;人才引进启动基金(批准号:20080302);天津市自然科学基金重点项目(批准号:06YFJZJC01200)资助

摘　　要：利用毫秒脉冲激光辐照石墨悬浮液制备了超细碳纳米颗粒,经过有机聚合物PEG 2000N的表面修饰,碳纳米颗粒发出了较强的可见光,并具有双光子激发的特征.利用硫酸奎宁作参比,测得碳纳米颗粒的荧光量子产率为6.3%.石墨颗粒通过吸收激光能量快速升温并升华,形成了大量的碳蒸气;在周围液体介质的冷却下,通过凝聚形成了碳纳米颗粒.由于尺寸量子限制效应,经过有机聚合物修饰后,碳纳米颗粒表面产生了能量势阱,导致了碳纳米颗粒的可见光发射.发光的碳纳米颗粒具有无毒、化学惰性和良好的生物相容性,在生物医药领域具有重要的应用价值.Uhrafine carbon nanoparticles were prepared by irradiating graphite suspension employing millisecond pulsed laser. Carbon nanoparticles emitted strong visible light after surface modification using PEG 2000. The characteristic of two-photon fluorescence was detected in the experiment. Fluorescence quantum yield of carbon nanoaprticles was 6. 3% employing quinine sulfate in 0. 1 mol/L H2SO4 as the standard reference sample. Graphite particles were heated up and sublimed by laser energy absorption; therefore, a large amount of carbon vapors were produced. After pulse duration, the carbon vapors cooled quickly under the liquid medium and formed carbon nanopartieles by condensation. Surface energy traps were created on the carbon nanoparticles after surface modification and resulted in the visible light emission due to the quantum confinement effects. Fluorescent carbon nanoparticles show high potential on the application of biology labeling and life science due to many advantages such as low cytotoxicity, biocompatibility, and chemically inert.

关 键 词：碳纳米颗粒 发光 脉冲激光 

分 类 号：O613.71[理学—无机化学] O631[理学—化学]