活性阴离子聚合及其单体的研究进展  

Progress in Study of Monomers Used in Living Anionic Polymerization

作　　者：朱李继[1] 李杨[1] 王玉荣[1] 张春庆[1] 

机构地区：[1]大连理工大学高分子材料系,大连116012

出　　处：《高分子通报》2009年第8期14-23,共10页Polymer Bulletin

基　　金：国家自然科学基金资助项目(NO.20674007)

摘　　要：适用于活性阴离子聚合的单体拓展研究是有关活性阴离子聚合的一项重要的研究工作。本文重点介绍了近十年在活性阴离子聚合领域出现的新型单体的结构设计、合成及其聚合过程的研究进展。文中涉及到的新型单体主要包括非(弱)极性类单体、极性单体及其它单体。进一步细分,非(弱)极性类单体分为苯乙烯衍生物类单体和丁二烯衍生物类单体,极性单体中含有丙烯酸酯类单体、丙烯酰胺类单体、氯乙烯以及N-乙烯基咔唑,其它单体包括异氰酸酯类、烯酮类以及杂环类单体。最后本文对上述这些新型单体中的一些单体用于复杂大分子拓扑结构的设计合成情况也作了简要介绍。The expanding of the monomers used in Therefore, this paper describes recent research advances living anionic polymerization is important to this field. related to structure design, synthesis and polymerization processes of novel monomers used in anionic polymerization. These monomers are nonpolar （or weak polarity） monomers, polar monomers and the other monomers. The nonpolar（or weak polarity）monomers are styrene derivatives and 1,3-butadiene derivatives; The polar monomers are acrylate Compounds, acrylamide Compounds, chloroethylene and N-vinyl carhazole; The other monomers are isocyanate esters, enone compounds and heterocyclic Compounds. And this paper also briefly introduces macromolecular architectures of some of the monomers mentioned above by means of living anionic polymerizations.

关 键 词：活性阴离子聚合 新单体设计合成 聚合过程 

分 类 号：O631[理学—高分子化学]