含手性基团的β-二酮及其铜(Ⅱ)配合物的合成  

Synthesis of βDiketones and Their Copper(Ⅱ)Compleses Containing Chiral Substituents

作　　者：原现瑞[1] 郭炳南[1] 朱湛[1] 

机构地区：[1]北京理工大学化工与材料学院

出　　处：《北京理工大学学报》1998年第3期393-396,共4页Transactions of Beijing Institute of Technology

摘　　要：目的研究含手性基团的β－二酮及其铜（Ⅱ）配合物的合成及其性质．方法合成三种新的含手性碳原子的β－二酮，１－对辛（壬、癸）氧基联苯基－３－３′－甲基戊基－１，３－丙二酮，及它们的铜（Ⅱ）配合物．确定化学结构后，通过在偏光显微镜下进行相变观察以及作ＤＳＣ分析，研究β－二酮及其铜（Ⅱ）配合物的相态变化．结果三种β－二酮配体均呈现双变Ｓ相液晶，而它们的铜（Ⅱ）配合物却没有表现出液晶性质．结论随着１－对烷氧基联苯基－３－３′－甲戊基－１，３－丙二酮配体的３位基团增大，它们的铜配合物的液晶性质消失．Aim To investigate the synthesis and properties of βdiketones and their copper(Ⅱ) complexes containing chiral substituents Methods Three new βdiketones (+)1(pnalkoxylbiphenyl)33′methylpentyl1,3dione,nalkoxyl:C8H 17 O,C9H 19 O,C 10 H 21 O and their copper (Ⅱ) complexes were prepared Their chemical stuctures were characterized and thermal behaviours were studied by polarizing microscope and differential scanning calorimetry Results The three ligands exhibit enantiotropic S mesophase and their copper (Ⅱ) complexes have no mesophase Conclusion The enlarged 33′methyl pentyl of the βdiketones results in the loss of mesophases of their Cu(Ⅱ) complexes 

关 键 词：二酮 手性基团 Β-二酮 铜配合物 液晶 

分 类 号：O614.121[理学—无机化学] O753.2[理学—化学]