双核金属酞菁配合物对Li／SOCl2电池的影响  

Effects of binuclear metal phthalocyanine compounds to Li/SOCl_2 battery

作　　者：王继锋[1] 赵建社[1] 马素杰[2] 李要民[2] 

机构地区：[1]西北大学化学系,合成与天然功能分子化学教育部重点实验室,陕西西安710069 [2]西安机电信息研究所,陕西西安710065

出　　处：《电池》2009年第4期211-213,共3页Battery Bimonthly

基　　金：国家自然科学基金(20671076);国家科技支撑计划课题(2007BAB17B02)

摘　　要：用微波法合成了双核金属酞菁配合物M2L[M=Mn（Ⅱ）、Fe（Ⅱ）、Co（Ⅱ）、Ni（Ⅱ）和Cu（Ⅱ），L为含硝基的酞菁环C65H24N22O13]，用元素分析、紫外．可见吸收光谱和红外光谱等方法对结构进行了分析。考察了它们对锂／亚硫酰氯（Li／SOCl2）电池放电性能的影响，并探讨了催化机理。除锰酞菁外，其他配合物具有较好的催化活性，电池的平均放电电压升高约0．2—0．3V，容量提高30％～80％。Binudear metal phthalocyanine compounds M2L[ M = Mn（ Ⅱ）, Fe（ Ⅱ ）, Co（ Ⅱ ）, Ni（ Ⅱ）and Cu（ H ）, L was phthalocyanine ring containing hexa-nitro C65H24 N22 O13 ] were synthesized by microwave process. Their structures were analyzed by element analysis, UV-vis absorption spectrum and infrared spectrum techniques. Their effects to the performance of lithium/thionyl chloride（ Li/SOCl2）battery were investigated and the catalytic mechanism was discussed. The others had fine catalytic activity exocpt Mn2（ Ⅱ ）L,the average discharge voltage of the battery increased about 0.2 - 0.3 V,the capacity improved 30%-80%.

关 键 词：过渡金属 双核金属酞菁配合物Li/SOCl2电池 催化机理 

分 类 号：TM911.1[电气工程—电力电子与电力传动]