反式9,10-二氢-9,10-二苯基-9,10-菲二醇包结性能的研究  

Study on Inclusion Phenomena of trans - 9,10 - Dihydro - 9, 10-diphenyl phenanthrene - 9,10 - diol as Host Molecule

作　　者：郭文生[1] 朱峰[2] 玉占君[1] 武跃[1] 康文俊[3] 吕扬[3] 郭放 郑启泰[3] 

机构地区：[1]辽宁师范大学化学系,大连116029 [2]佛山科学技术学院化学与化工系,佛山528000 [3]中国医学科学院药物研究所,北京100050

出　　处：《化学学报》1998年第8期812-818,共7页Acta Chimica Sinica

基　　金：国家自然科学基金(39370810)

摘　　要：合成了一种具有整形结构的反式－９，１０－二氢－９，１０－二苯基－９，１０－菲二醇（１）作为主体分子，它能与许多有机小分子化合物，诸如ＤＭＦ，ＤＭＳＯ，吡啶，哌啶，喹啉，异喹啉等包结化合物，本文还报道了这些包结化合物的ＩＲ，粉末ＸＲＤ的表征，用ＨＮＭＲ测定了它们的分子摩尔比，ＤＭＦ包结物的单晶四圆Ｘ衍射结果表明主体分子１与客体分子形成的包结物为配位笼状包合物。A compoumd having chela shape, trans-9, 10-dihydro-9, 10-diphenyl phenanthrene- 9,10 - diol(1), was synthesized. It could form the inclusion compounds with various small organic molecules such as DMF, DMSO, pyridine, piperidine, quinoline isoquinline. These inclusion compounds were confirmed by means of IR and powder XRD, and their host-guest molar ratio was determined by 1H NMR. The results of four circle XRD for single cyrstal of the inclusion compound of the host molecule (1) with DMF shown that the host molecule(1)formed coordinatoclathrate with guest molecules.

关 键 词：反式 二氢 二苯基 菲二醇 包结化合物 配位笼状 

分 类 号：O625.34[理学—有机化学]