三元体系Zn(ClO_4)_2-BAPHDCA-H_2O(30℃)的相平衡研究及Zn(BAPHDCA)(ClO4)2·2H2O的合成与表征  

A Study of the Ternary System of Zn(ClO 4) 2 BAPHDCA H 2O at 30 ℃ and the Preparation and Characterization of the Zn(BAPHDCA)(ClO 4) 2·2H 2O

作　　者：崔斌[1] 唐宗薰[1] 郭志箴[1] 陈开勋[1] 

机构地区：[1]西北大学化学系

出　　处：《高等学校化学学报》1998年第8期1208-1210,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金;北京大学稀土材料化学及应用国家重点实验室资助

摘　　要：安替比林（ＡＰ）及其４位取代衍生物与各种稀土盐及过渡金属盐之间的化学行为已有广泛的研究［１，２］．为了进一步考察安替比林类衍生物与过渡金属盐形成双核或多核化合物的可能性，我们合成了新型配体Ｎ，Ｎ′－二安替比林－１，６－己二酰胺（ＢＡＰＨＤＣＡ）［３］...The solubilities and the refractive indexes of the saturated solutions of the titled system at 30 ℃ have been studied and the corresponding equilibrium diagram and refractive index diagram were constructed, both solubility curves and refractive index curves of the system consist of three branches, corresponding to BAPHDCA, Zn(BAPHDCA)(ClO 4) 2·2H 2O and Zn(ClO 4) 2 ·6H 2O, respectively. The Zn(BAPHDCA)(ClO 4) 2·2H 2O is a new compound, which was characterized by chemical and elemental analysis, IR spectra and thermoanalysis.

关 键 词：相平衡 三元体系 水 BAPMDCA 锌 高氯酸锌 

分 类 号：O614.241[理学—无机化学] O642.42[理学—化学]