EOC-g-MAH共混增韧SGF/PP泡沫复合材料的制备及力学性能  

Preparation and mechanical properties of SGF/PP foam composites toughened by EOC-g-MAH

作　　者：杨继年[1] 李子全[1] 刘晓蓓[1] 王凌岩[1] 梁宇翔[1] 刘劲松[1] 

机构地区：[1]南京航空航天大学材料科学与技术学院,江苏南京210016

出　　处：《化工学报》2009年第9期2392-2397,共6页CIESC Journal

基　　金：南京航空航天大学科研创新基金项目(S0279-061)~~

摘　　要：采用型内二次发泡工艺制备了马来酸酐接枝乙烯-1-辛烯共聚物(EOC-g-MAH)共混增韧短玻璃纤维(SGF)/聚丙烯(PP)泡沫复合材料,考察了EOC-g-MAH含量对复合材料的泡孔形貌、微观结构和力学性能的影响。结果表明,EOC-g-MAH的引入改善了泡沫体的发泡效果,平均孔径减小约35%,泡孔密度提高近4倍且分布均匀。SGF与基体间的界面结合得到显著增强,且EOC-g-MAH在SGF表面形成了颗粒黏附结构,大幅提高了SGF/PP泡沫复合材料的冲击韧度,并在质量分数为8%时达到最大值,增幅为77%。随着EOC-g-MAH质量分数的增加,SGF/PP泡沫复合材料的抗弯强度先增加后降低,而压缩强度则呈近似线性下降的变化趋势。The short glass fiber（SGF）/polypropylene（PP）foam composites toughened by maleic anhydride grafted ethylene-1-octene copolymer（EOC-g-MAH）were prepared via post-foaming process in designed dies.The influence of EOC-g-MAH content on the cellular morphology,microstructure and mechanical properties of composites were investigated.The results indicated that the outstanding improvement in foaming effect was realized by the addition of EOC-g-MAH with a 35% reduction for average cell size and nearly four-fold increase in cell density. The interracial adhesion between SGF and matrix was enhanced. More im surface of SGF was observed. portantly, a novel morphology of EOC-g-MAH particles adhered to the The impact toughness of the SGF/PP foam composites was improved significantly and the peak value with a 77% increase was obtained when the mass fraction of EOC-g-MAH was added up to 8%. The flexural strength of SGF/PP foam composites was increased first and then decreased. However, the compressive strength exhibited an almost linear decline with the increase of the EOC-g-MAH.

关 键 词：聚丙烯 泡沫复合材料 增韧 界面结合 

分 类 号：TQ328.9[化学工程—合成树脂塑料工业]