顺式和反式-2-氨基-3-氰基-4-苯基-1-(4'-甲基苯基)-2-环戊烯-1-醇的合成和晶体结构  

Synthesis and Crystal Structure of cis and trans-2-Amino-3-cyano-4-phenyl-1-(4＇-methylphenyl)-2-cyclopentene-1-ol

作　　者：史达清[1] 路再生[1] 沐来龙[1] 戴桂元[1] 

机构地区：[1]徐州师范大学化学系,徐州221009

出　　处：《化学学报》1998年第6期550-556,共7页Acta Chimica Sinica

基　　金：江苏省青年科技基金资助项目

摘　　要：用低价钛试剂(TiCl_4-Zn)与4,4-二氰基-3-苯基-1-(4＇-甲基苯基)-1-丁酮反应合成了顺式和反式-2-氨基-3-氰基-4-苯基-1-(4＇-甲基苯基)-2-环戊烯-1-醇。The cis and trans - 2 - amino - 3 - cyano - 4 - phenyl - 1 - (4' - methylphenyl) - 2 - cyclopentene - 1 - ols were synthesized by reaction of low - valent titanium reagent (TiCl4 -Zn) with 4,4- dicyano - 3 - phenyl - 1 - (4' - methylphenyl) - 1 - butanone. Their configurations were determined by X- ray analysis.

关 键 词：氨基 氰基 苯基 甲基苯基 环戊烯醇 合成 晶体 

分 类 号：O624.32[理学—有机化学]