New mesogenic Schiff base esters comprising benzothiazole moiety:Synthesis and mesomorphic properties  

New mesogenic Schiff base esters comprising benzothiazole moiety:Synthesis and mesomorphic properties

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作  者:Sie Tiong Ha Teck Ming Koh Guan Yeow Yeap Hong Cheu Lin Jun Kit Beh Yip Foo Win Peng Lim Boey 

机构地区:[1]Faculty of Engineering & Science,Universiti Tunku Abdul Rahman,Jln Genting Klang,Setapak 53300 Kuala Lumpur,Malaysia [2]Liquid Crystal Research Laboratory,School of Chemical Sciences,Universiti Sains Malaysia 11800 Minden,Penang,Malaysia [3]Department of Materials Science & Engineering,National Chiao Tung University,1001 Ta-Hsueh Road,Hsinchu 300,Taiwan [4]Faculty of Science,Engineering & Technology,Universiti Tunku Abdul Rahman,Jln Universiti,Bandar Barat 31900 Kampar,Perak,Malaysia

出  处:《Chinese Chemical Letters》2009年第9期1081-1084,共4页中国化学快报(英文版)

基  金:Universiti Tunku Abdul Rahman(UTAR)for the research facilities andfinancial support(No.6202/K06);the Malaysian Toray Science Foundation(No.4359/000)

摘  要:A homologous series of Schiff base esters, 6-methoxy-2-(2-hydroxy-4-alkanoyloxybenzylidenamino)benzothiazoles, compris- ing a benzothiazole moiety as the core was synthesized. All the members of this series exhibited an enantiotropic nematic phase. The azomethine linkage along with the lateral hydroxyl and terminal methoxyl groups were found to exert an effect on the mesomorphic properties. 2009 Sie Tiong Ha. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.A homologous series of Schiff base esters, 6-methoxy-2-(2-hydroxy-4-alkanoyloxybenzylidenamino)benzothiazoles, compris- ing a benzothiazole moiety as the core was synthesized. All the members of this series exhibited an enantiotropic nematic phase. The azomethine linkage along with the lateral hydroxyl and terminal methoxyl groups were found to exert an effect on the mesomorphic properties. 2009 Sie Tiong Ha. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

关 键 词:Schiff bases BENZOTHIAZOLES MESOMORPHIC NEMATIC Structure-liquid crystal property relationship 

分 类 号:O621.2[理学—有机化学]

 

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