Syntheses and Crystal Structures of One-dimensional Ni(Ⅱ) Complexes with 5-Tert-butyl Isophthalic Acid  

作　　者：樊耀亭 李波 马录芳 王利亚 

机构地区：[1]Department of Chemistry,Zhengzhou University [2]College of Chemistry and Chemical Engineering,Luoyang Normal University

出　　处：《Chinese Journal of Structural Chemistry》2009年第9期1061-1066,共6页结构化学（英文）

基　　金：supported by the National Natural Science Foundation of China (Nos.20771026 and 20771054);the Henan Tackle Key Problem of Science and Technology (Nos.072102270030 and 072102270034);the Foundation of Education Committee of Henan Province (2006150017 and 2008A150018)

摘　　要：Two new Ni（ Ⅱ） coordination polymers, {[Ni（tbip）（bipy）（H2O）]-0.5H2O}n 1 and [Ni（tbip）（phen）（H2O）]n 2 （Hatbip = 5-tert-butyl isophthalic acid, bipy = 2,2＇-bipyridine, phen = 1,10-phenanthroline）, have been synthesized under hydrothermal conditions and characterized by elemental analysis, X-ray diffraction, and IR spectroscopy. In the two polymers, H2tbip acts as a tridentate ligand. Compound 1 has a tbip bridged 1-D linear chain which is extended by hydrogen bonds into a 1-D double chain, while compound 2 exhibits a 1-D zigzag chain.Two new Ni（ Ⅱ） coordination polymers, {[Ni（tbip）（bipy）（H2O）]-0.5H2O}n 1 and [Ni（tbip）（phen）（H2O）]n 2 （Hatbip = 5-tert-butyl isophthalic acid, bipy = 2,2＇-bipyridine, phen = 1,10-phenanthroline）, have been synthesized under hydrothermal conditions and characterized by elemental analysis, X-ray diffraction, and IR spectroscopy. In the two polymers, H2tbip acts as a tridentate ligand. Compound 1 has a tbip bridged 1-D linear chain which is extended by hydrogen bonds into a 1-D double chain, while compound 2 exhibits a 1-D zigzag chain.

关 键 词：Ni（Ⅱ） complex 5-tert-butyl isophthalic acid crystal structure 

分 类 号：O621.3[理学—有机化学]