Galvinoxyl相转移催化合成芳基双偶氮酮类化合物  

Galvinoxyl Phase Transfer Catalyst Synthesis Aryl Carbodiazone Compounds

作　　者：李建平[1] 王玉炉[1] 王晓阳[1] 王彩兰[1] 王红[1] 马东兰[1] 赵淑华 

机构地区：[1]河南师范大学化学系,新乡453002

出　　处：《有机化学》1998年第5期452-455,共4页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金;河南省自然科学基金

摘　　要：以二芳基卡巴肼为原料,以Galvinoxyl(自由基)为相转移催化剂,高产率地制得了芳基双偶氮酮类化合物。讨论了反应的可能机理。Eight aryl carbodiazone compounds were synthesized by the reaction of aryl substituted carbazide compounds with a Galvinoxyl(radical) between two phase in good yield. A phase transfer catalytic mechanism is suggested.

关 键 词：相转移催化 合成 芳基 双偶氮酮 Gawlvinoxyl 

分 类 号：O625.65[理学—有机化学]