N,N-二甲酰基二硫代氨基甲酸根金属配合物的研究  

STUDY ON THE TRANSITION METAL COMPLEXES OF N,N DIFORMYLDITHIOCARBAMATE

作　　者：贺玲[1] 史清芳[1] 苟少华[1] 方江邻[1] 龚雁 

机构地区：[1]南京大学配位化学研究所配位化学国家重点实验室

出　　处：《无机化学学报》1998年第3期360-365,共6页Chinese Journal of Inorganic Chemistry

摘　　要：本文首次报道了一系列Ｎ，Ｎ－二甲酰基二硫代氨基甲酸根为配体的过渡金属配合物，对它们进行了化学分析、光谱表征和磁性质研究。研究结果表明，在配合物中，配体二硫代氨基甲酸根一般为较弱的双齿配位。A series of novel transition metal complexes of N,N diformyldithiocarbamate, the first example of a dithiocarbamate with two N substituted electron withdrawing groups, have been prepared and characterized by chemical analysis as well as spectral and magnetic studies A thorough inspection of the spectroscopic and magnetic data of these novel compounds demonstrates the weakly bidentate bonding mode of the carbodithioato ligand in the complexes

关 键 词：过渡金属 二甲酰基 二硫代氨基 甲酸根 配合物 

分 类 号：O614[理学—无机化学]