一个含铜(Ⅱ)四氮大环阳离子和锰(Ⅱ)一维链阴离子化合物{[Cu(trans[14]diene)SCN]_2Mn(SCN)_4(4,4'-bipy)·4H_2O}_n的合成和结构  被引量:5

Synthesis and Structure of a New 4,4 Bipy bridged One Dimensional Hetero metallic Compound with Macrocycle Ligand { Cu( trans 14 diene)SCN 2Mn(SCN) 4(4,4 bipy)\54H 2O} n

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作  者:沈昊宇[1] 孙柏旺[1] 廖代正[1] 姜宗慧[1] 阎世平[1] 王耕霖[1] 郁开北[2] 

机构地区:[1]南开大学化学系 [2]中国科学院成都分院分析测试中心

出  处:《高等学校化学学报》1998年第10期1533-1536,共4页Chemical Journal of Chinese Universities

基  金:国家自然科学基金;高等学校博士点专项基金

摘  要:报道了一维化合物{[Cu(trans[14]diene)SCN]2Mn(SCN)4(4,4′-bipy)·4H2O}n(trans[14]diene为5,7,7,12,14,14-六甲基-1,4,8,11-四氮杂十四环-4,11-二烯,4,4′-bipy为4,4′-联吡啶)的合成、表征和结构分析.该晶体属三斜晶系,具有P1空间群.a=0.95920(10)nm,b=1.06800(10)nm,c=1.7316(2)nm,α=84.400(10)°,β=74.850(10)°,γ=69.650(10)°,V=1.6053(3)nm3,Z=1,Dc=1.365g/cm3,F(000)=691,最终R[I>2σ(I)]=0.0474,R(全部)=0.0625,GOF(F2)=1.222.该化合物含[Mn(SCN)4(4,4′-bipy)n]2-链和两个[Cu(trans[14]diene)SCN]+阳离子.The studies of one dimensional compounds have attracted chemists for many interests, because they are not only important for molecular designing and magnetic materials, but also the basis of studying high dimensional compounds. Here we reported the preparation and X ray analysis of 4,4 bipyridine bridged one dimensional compound { Cu( trans 14 diene)SCN 2\5 Mn(SCN) 4(4,4 bipy)\54H 2O} n , where( trans 14 diene)=5,7,7,12,14,14 hexamethyl 1,4,8,11 tetraazacyclotetradeca 4,11 diene, 4,4 bipy=4,4 bipyridine. It crystallized in the triclinic system, space group P 1, with a = 0.959 20(10) nm, b = 1 068 00(10) nm, c = 1 731 6(2) nm, α =84 400(10)°, β =74 850(10)°, γ =69 650(10)°. V =1 605 3(3) nm 3, Z =1 , D c =1 365 g/cm 3, F (000)=691, final R I>2σ(I) =0 047 4, wR 1 =0 134 8, R (all data)=0 062 5, wR 2=0 146 8, GOF( F 2)=1.222. This complex is consist of a Mn(SCN) 4\5 (4,4 bipy) 2- chain and two Cu( trans 14 diene) SCN + ions.

关 键 词:结构 联吡啶 一维化合物   四氧大环 合成 

分 类 号:O614.121[理学—无机化学] O614.711[理学—化学]

 

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