Os(Ⅱ)配合物的电化学性质及其电子能级结构  

Electrochemical Properties and Electronic Energy Level Structure of Os(Ⅱ) Complexes

作　　者：吴芳[1,2] 田文晶[1,2] 张厚玉[1,2] 马於光[1,2] 沈家骢[1,2] 支志明[1,2] 

机构地区：[1]吉林大学超分子结构与谱学开放实验室 [2]香港大学化学系

出　　处：《高等学校化学学报》1998年第10期1671-1673,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金

摘　　要：采用电化学循环伏安法和荧光光谱研究了系列Ｏｓ（Ⅱ）配合物的电化学性质及分子结构对其电子能级结构的影响．The effects of molecular structure on the electrochemical properties and the electronic structure of four Os(Ⅱ) complexes have been explored by cyclic voltammetry and fluorescence spectra. The results indicate that the oxidation and reduction properties and the electronic energy level structure of the complexes can be changed by either introducing different substituents into the bipyridine ligand or replacing the bipyridine ligand with phenanthroline. The above conclusion were confirmed by the photospectroscopy measurements.

关 键 词：电化学 分子结构 电子结构 锇配合物 

分 类 号：O614.824[理学—无机化学]