(2,2-双二茂铁基丙烷)-6-甲酰胺的合成与表征  

Synthesis and characterization of (2,2-bisferrocenylpropane)-6-acidamide

作　　者：杜青慧[1] 温国华[1] 温国永[1] 付渊[1] 张伟[1] 王晓莉[2] 

机构地区：[1]内蒙古大学化学化工学院,内蒙古呼和浩特010021 [2]内蒙古化工职业学院实习实训中心,内蒙古呼和浩特010011

出　　处：《化学试剂》2009年第10期828-830,共3页Chemical Reagents

基　　金：内蒙古自然科学基金资助项目(200711020204)

摘　　要：以2,2-双二茂铁基丙烷作为母体,经过邻氯苯甲酰化制得酰化产物,酰化产物在叔丁醇钾的作用下合成相应的甲酸,该甲酸与三氯化磷作用得到酰氯,并以此合成了一系列的甲酰胺,通过元素分析、红外光谱和核磁共振氢谱对这些化合物的结构进行了表征。In this paper,the acylation of 2,2-bisferrocenylpropane with acyl chloride resulted in the acylated product,which upon reaction with t-C4H9OK in ethylene glycol dimethyl ether solution yielded corresponding carboxylic acid,then acylfluoride was synthesized by the reaction of carboxylic acid with phosphorus trichloride,furthermore,a series of acidamides were prepared from carboxylic acid and 2,2-bisferrocenylpropane.These new compounds were characterized by elemental analysis,IR and ^1HNMR.

关 键 词：2 2-双二茂铁基丙烷 酰胺 合成 表征 

分 类 号：O624.5[理学—有机化学]