4-氨基-3,5-二(2-羟基苯基)-1,2,4-三唑的合成、表征及其光物理性能  

Synthesis,Characterization and Photophysical Properties of 4-Amino-3,5-bis(o-Hydroxyphenyl)-1,2,4-Triazole

作　　者：陈连清[1] 李群丽[1] 施超[1] 渠星宇[1] 

机构地区：[1]中南民族大学化学与材料科学学院,武汉430074

出　　处：《中南民族大学学报（自然科学版）》2009年第3期19-24,共6页Journal of South-Central University for Nationalities：Natural Science Edition

基　　金：国家自然科学基金资助项目(20702064);中南民族大学自然科学基金资助项目(YZZ07007)

摘　　要：为探索1,2,4-三唑衍生物的合成及光物理性能,通过改进的双酰肼环化法合成了4-氨基-3,5-二(2-羟基苯基)-1,2,4-三唑,分别讨论了反应物的投料比、反应温度、反应时间及催化剂对产率的影响;对目标化合物进行了IR,1H NMR,MS和元素分析等表征,并测试了其紫外、荧光,探讨了光物理性能.To explore the synthesis and photophysical properties of 1, 2, 4-triazole derivatives, 4-amino-3, 5-bis （o-hydroxyphenyl）-l, 2, 4-triazole was synthesized by improved methods of dihydrazide cyclization. The effect of reactant ratio, reaction temperature, reaction time and amount of catalyst on the yield were discussed. Its structure has been fully characterized by FT-IR,1H NMR, MS and elemental analysis. The electronic absorption and fluorescence properties of the object compound have been investigated.

关 键 词：1 2 4-三唑衍生物 合成 光物理性能 

分 类 号：TB383[一般工业技术—材料科学与工程]