哌嗪合成中催化剂的研究  

Study on the Catalyst for the Synthesis of Piperazine

作　　者：王多禄[1] 许正双[1] 陈立功[1] 冯亚青[1] 祝源生 孙春光 于运勇 

机构地区：[1]天津大学化工学院

出　　处：《化学工业与工程》1998年第4期25-29,共5页Chemical Industry and Engineering

摘　　要：以Ｎ－β－羟乙基乙二胺为原料合成哌嗪，研制出一种高活性和选择性铜／载体型催化剂，并探讨了催化剂组成等因素对反应的影响。在Ｃｕ－Ｃｒ－Ｍｎ／γ－Ａｌ２Ｏ３催化剂和氢气的存在下，于１８０℃下反应２ｈ，则原料转化率达９８％以上，哌嗪收率为８８％。This paper is concerned about the catalyst for the synthesis of piperazine with N (β hydroxyl ethyl) ethylenediamine (HEDA) as raw material.A new supported copper catalyst with high reactivity and selectivity was developed.In the presence of Cu Cr Mn/γ Al 2O 3 catalyst and under hydrogen pressure at 180℃,the reaction proceeded effectively to give piperazine in 2 hours with a yield as high as 88%,while the conversion was over 98%.

关 键 词：铜 催化剂 哌嗪 载体型 

分 类 号：TQ254.15[化学工程—有机化工] TQ426.65