杯芳烃-卟啉化合物及其锌、钯配合物的制备与成膜性能研究  

Synthesis of calixarene-porphyrin and its Zinc,Palladium complexes and investigations of their capabilities for film composition

作　　者：张琳[1] 温燕梅[1] 谢建英[1] 

机构地区：[1]广东海洋大学理学院,广东湛江524088

出　　处：《分子科学学报》2009年第5期361-364,共4页Journal of Molecular Science

摘　　要：将广泛用作分子构架和分子载体的杯芳烃和卟啉结合,合成了具有更多功能和用途的杯芳烃-卟啉化合物及其锌、钯配合物,并成功地在气/液界面得到它们的单分子膜,并对其成膜性能作了初步的探讨.结果表明,无论是杯芳烃-卟啉化合物还是它的锌、钯配合物均能形成稳定的单分子膜.The widely used molecular framework and molecular carrier,Calixarene and porphyrin,are combined to synthesize calixarene-porphyrin compound and its zinc and palladium complexes.Their monolayer films have been successfully composed and their film forming abilities have been primarily discussed.The results indicate that either calixarene-porphyrin compound or its zinc and palladium complexes can form steady monolayer films.

关 键 词：杯芳烃 卟啉 气/液界面 膜 

分 类 号：O641[理学—物理化学]