正电性磁性氧化铁胶粒负载钯催化的Suzuki偶联反应  

Suzuki Coupling Reaction Catalyzed by Palladium Supported on Positively Charged Colloids of Magnetic Iron Oxide

作　　者：刘诗咏[1] 吴家守[1] 蒋华江[1] 金正能[1] 姜玄珍[2] 

机构地区：[1]浙江省台州学院城东校区医化学院,临海317000 [2]浙江大学玉泉校区理学院化学系,杭州310027

出　　处：《有机化学》2009年第10期1587-1592,共6页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.20476092);台州学院基金(No.09ZD12)资助项目

摘　　要：发展了一种超顺磁性Fe3O4纳米粒子负载Pd0的简易方法.利用Fe3O4溶胶带正电荷的特性,将负离子PdCl42-通过静电作用吸附在Fe3O4胶体粒子表面(PdCl24-/Fe3O4),以抗坏血酸(Vc)进一步还原即得到载有金属Pd团簇的Fe3O4胶体粒子(Pd0/Fe3O4).该磁性载体负载的Pd催化剂对Suzuki反应表现出良好的催化活性,且在反应后,可方便地通过永久磁铁将催化剂从反应体系中分离出来,进行循环使用.试验表明,该催化剂在循环使用五次后反应活性无明显下降.进一步试验发现,这种磁性纳米粒子负载的金属钯对一系列卤代芳烃的Suzuki偶联反应均表现出较优的催化活性.A facile way to combine Pd^0 with superparamagnetic Fe3O4 nanoparticles （NP） was provided, in which PdCl4^2- was immobilized directly on the cationic Fe3O4 colloids through electrostatic interaction （ PdCl4^2-/Fe3O4）. Further reduction of the PdCl4^2-/Fe3O4 NP by vitamin C resulted in Pd^0/Fe3O4 NP. These magnetic NP-supported Pd^0 clusters showed high efficiency toward Suzuki reactions. After reactions, the Pd^0/Fe3O4 NP could be facilely recycled by permanent magnet. This catalyst could be reused for 5 times without significant loss in catalytic activity. Suzuki coupling reaction of a variety of aryl halides was also catalyzed efficiently by this magnetic NP supported Pd^0.

关 键 词：钯 纳米粒子 正电荷溶胶 磁性氧化铁 SUZUKI反应 

分 类 号：O643.32[理学—物理化学]