先进复合材料用新型RTM树脂基体的研究  

Research on New RTM Resin Matrix for Advanced Composites

作　　者：孟庆辉[1] 顾嫒娟[1] 梁国正[1] 袁莉[1] 

机构地区：[1]苏州大学材料与化学化工学部,苏州215123

出　　处：《武汉理工大学学报》2009年第21期1-4,共4页Journal of Wuhan University of Technology

基　　金：国家自然科学基金(50773048;50873073);江苏省"333高层次人才培养工程"科研项目

摘　　要：设计并制备了一种先进复合材料用新型高性能RTM树脂基体,它以二烯丙基双酚A(BA)改性双马来酰亚胺(BMI)为基本组成,采用经γ-缩水甘油醚氧丙基三甲氧基硅烷(KH560)水解而成的超支化聚硅氧烷(HBPSi)为活性稀释剂。系统探讨了树脂的工艺性能和固化物的耐热性和韧性。研究结果表明,HBPSi的加入不仅可以有效降低改性BMI树脂的粘度,而且可以提高固化物的耐热性和韧性。A new kind of high performance matrices for advanced composites via RTM technique was developed,which was made up of diallyl bisphenol A modified bismaleimide resin and hyperbranched polysiloxane（HBPSi）,and coded as BMI/BA/HBPSi.The effect of HBPSi content on the processing characteristics,thermal properties and toughness of BMI/BA/HBPSi system was investigated systematically.Results show that the incorporation of HBPSi could not only reduce the viscosity of BMI/BA,but also improve the impact strength and heat resistance.

关 键 词：RTM 双马来酰亚胺树脂 超支化聚硅氧烷 韧性 热性能 

分 类 号：TQ323.7[化学工程—合成树脂塑料工业] TQ324.2