弹状流对陶瓷膜超滤葡聚糖水溶液的影响  

Effect of slug flow on dextran ultrafiltration in ceramic membrane process

作　　者：张峰[1] 景文珩[1] 邢卫红[1] 

机构地区：[1]南京工业大学膜科学技术研究所,材料化学工程国家重点实验室,江苏南京210009

出　　处：《化工学报》2009年第11期2792-2797,共6页CIESC Journal

基　　金：国家自然科学基金重点项目(20636020);国家重点基础研究发展计划项目(2009CB623403);国家高技术研究发展计划项目(2006AA03Z534 );中国博士后科学基金项目(20060400927);江苏省博士后科研资助计划项目(0601023B)~~

摘　　要：为降低膜污染和浓差极化需维持较高膜面流速,能耗较高。将气升式外循环引入膜过程,可有效降低浓差极化和能耗。实验考察了曝气量对渗透通量的影响,当曝气量为400L.h-1时,与相同液速条件下单相流错流过滤相比较,膜通量提升87%;进一步增大曝气量,膜通量增加趋势变缓。对气升式膜过滤过程的水力学特性进行了研究,在弹状流条件下,气液两相流可有效提高膜面剪切力,增强膜面传质。在较低流速下,曝气可有效降低膜污染阻力,提高膜通量。结合气液两相流理论和膜过滤阻力模型,分析了弹状流提升膜通量的机理。The ceramic membrane process has been encountered with a problem of high energy consuming owing to that high crossflow velocities are necessary for the concentration polarization and membrane fouling control. On the other hand, the external loop airlift reactor is widely used in the field of chemical engineering. Thus, the application of air sparging in dextran ultrafiltration with ceramic membrane process is studied at different gas flow rates （QG）. 87% increase in permeation flux was achieved while filtering 2 g .h^-1 dextran （2× 10^6） solution with the airlift crossflow operation of QG =400 L .h^-1. Hydrodynamics of the gas-liquid two-phase flow was characterized and the flux enhancement mechanism in the case of slug flow in tubular ceramic membrane was discussed.

关 键 词：气升 超滤 陶瓷膜 浓差极化 葡聚糖 

分 类 号：TQ052[化学工程]