表面活性剂对环氧树脂固化反应及性能的影响  

The Effect of Surfactant on the Cure Reactions of an Epoxy

作　　者：袁钻如[1] 谢鸿峰[2] 刘承果[2] 曹宏[2] 程镕时[2,3] 

机构地区：[1]南京大学现代分析中心 [2]南京大学化学化工学院教育部介观化学重点实验室,高分子科学与工程系,江苏南京210093 [3]华南理工大学材料学院,广东广州510641

出　　处：《高分子材料科学与工程》2009年第11期97-99,103,共4页Polymer Materials Science & Engineering

基　　金：高等学校博士学科点专项科研基金(20070284054);南京大学技术创新基金项目(重大关键技术)(2009101)

摘　　要：用热分析手段研究了非离子型表面活性剂Triton X-100对4,4′-二氨基二苯甲烷环氧树脂(TGDDM)/4,4′-二氨基二苯基砜(DDS)环氧树脂固化行为和性能的影响。DSC非等温固化反应动力学研究表明,1%(质量分数,下同)的表面活性剂对固化反应有促进作用,但10%的表面活性剂抑制了固化反应。DSC的等温固化反应中,表面活性剂抑制固化反应的进行。TGA研究表明,表面活性剂的加入对环氧树脂热稳定性影响很小。DMTA研究结果说明,表面活性剂在环氧树脂中起到了增塑剂的作用,并且和环氧树脂是互容的,表面活性剂的加入使得环氧树脂的储存模量减小,玻璃化温度逐渐降低。The influence of nonionic surfactant, Triton X-100 on the cure behaviors and properties of tetraglycidyl 4,4＇-diaminodiphenyl methane （TGDDM） epoxy with 4, 4＇-diaminodiphenyl sulphone （DDS） was studied with thermal analytical methods. Non-isothermal cure kinetics of differential scanning calorimeter （DSC） showed that 1% surfactant exerts acceleration effect on the cure reaction of the epoxy, while 10% surfactant hinders the cure reaction. However, it showed that all surfactants hinder the cure reaction of the epoxy during the isothermal curing. The results of thermogravimetric analyser （TGA） showed that the incorporation of surfaetants has little effect on the thermal stability of the epoxy. Using dynamic mechanical thermal analysis （DMA）, it was determined that the surfactant acts as a plasticizer and is miscible with the epoxy system. The storage modulus decreases with the addition of surfactant and the glass transition temperature drops with the increasing of surfactant contents.

关 键 词：表面活性剂 环氧树脂 固化反应动力学 

分 类 号：TQ314.269[化学工程—高聚物工业]