Synthesis and characterization of yttrium hydroxide and oxide microtubes  

作　　者：WANG Shijin ZHONG Shengliang WEN Zubiao WANG Yuling WANG Shangping CHEN Jianjun XU Rong LUO Longfei 

机构地区：[1]College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

出　　处：《Rare Metals》2009年第5期445-448,共4页稀有金属（英文版）

基　　金：support from Projects under Scientific and Technological Planning of Education Office of Jiangxi Province, China.

摘　　要：Hexagonal microtubes with hexagonal phase Y（OH）3 were successfully synthesized by a facile solvothermal method at 160°C for 12 h in the absence of surfactants or templates via a crystal transformation route. Scanning electron microscopy （SEM） results demonstrate that the prepared hexagonal microtubes are with a wall thickness of 50-100 nm, an outer diameter of 1 μm, and lengths going up tens of micrometers. Cubic phase Y2O3 microtubes were obtained after thermal treatment of the Y（OH）3 microtubes at 700 oC for 4 h. Eu^3＋-doped Y2O3 microtubes with strong red emission at 610 nm were also prepared and their photoluminescence （PL） properties were studied. The possible mechanism for the formation of the microtubes was briefly discussed.Hexagonal microtubes with hexagonal phase Y（OH）3 were successfully synthesized by a facile solvothermal method at 160°C for 12 h in the absence of surfactants or templates via a crystal transformation route. Scanning electron microscopy （SEM） results demonstrate that the prepared hexagonal microtubes are with a wall thickness of 50-100 nm, an outer diameter of 1 μm, and lengths going up tens of micrometers. Cubic phase Y2O3 microtubes were obtained after thermal treatment of the Y（OH）3 microtubes at 700 oC for 4 h. Eu^3＋-doped Y2O3 microtubes with strong red emission at 610 nm were also prepared and their photoluminescence （PL） properties were studied. The possible mechanism for the formation of the microtubes was briefly discussed.

关 键 词：inorganic compounds chemical synthesis LUMINESCENCE MICROSTRUCTURE 

分 类 号：TQ174.758[化学工程—陶瓷工业] Q245[化学工程—硅酸盐工业]