杭州市区大气臭氧浓度变化及气象要素影响  

The Variation of Ozone Concentrations in Urban Districts of Hangzhou and Their Relationship with Meteorological Factors

作　　者：洪盛茂[1] 焦荔[1] 何曦[1] 周春雨[2] 

机构地区：[1]杭州市环境监测中心站,杭州310007 [2]杭州市气象台,杭州310008

出　　处：《应用气象学报》2009年第5期602-611,共10页Journal of Applied Meteorological Science

基　　金：杭州市科技局重点项目(20051323B41)资助

摘　　要：利用2005—2007年杭州市区大气O3连续监测资料,分析了O3浓度变化特征,在此基础上结合气象观测资料,分析了大气O3与天气系统间的关系,建立了O3与气象要素间的多元回归方程。结果表明:2007年O3平均浓度和最大小时浓度分别为44μg.m-3和348μg.m-3,比上一年增加20%左右,超标现象也越来越严重;O3浓度有明显的季节变化,夏季高、冬季低;大气O3浓度超标主要出现在高压后部和高压控制等天气类型。在紫外线强度较强时O3浓度也高,二者呈显著正相关;对O3与各种气象因子进行多元回归分析表明:O3主要受到温度、相对湿度、日照等因素影响。Based on the observation data of near surface O3 and meteorological factors in 7 monitoring sites of Hangzhou urban area from 2005 to 2007,the O3 concentration and their temporal variation characteristics are researched.The peak hourly concentration and its nonattainment rate of Hangzhou are compared with those of other major cities at home and abroad.The variation of O3 concentration and its nonattainment rate under different weather conditions are studied,and the variation of O3 concentration with different levels of UV intense is discussed.The results show that the ozone concentration increases significantly year by year,the annual mean ozone concentration and the peak hourly concentration in 2007 are 44 μg·m-3 and 348 μg·m-3,respectively,showing a growth of about 20% from 2006.The ozone nonattainment rate in 2007 is 13.2%,about twice as high as that in 2006.The percentages of ozone nonattainment days from June to September are 75% in total nonattainment days.The appearing time of ozone nonattainment is from 10：00 to 18：00,and the most frequent appearing time of highest nonattainment concentration is around 14：00.The higher ozone nonattainment rate occurs in summer,primarily under the wind direction of SSE,lower in spring,still lower in fall,and the lowest value occurs in winter,taking on a very obvious seasonal variation trend.The variation of ozone concentration in sites differs during four seasons,showing highest concentration in summer and lowest in winter where concentration are higher,but on the others sites highest value occurs in spring and lowest in winter.The diurnal mean concentration during the rainy season is lower with effects of air mass and meteorological conditions brought by summer monsoon.The diurnal variation ranges of ozone concentration are different in four seasons,showing higher peak value and lower valley in summer and fall.The concentrations of peak and valley are all lower in winter.The diurnal variation range of higher concentration sites is bigger than that of lower conce

关 键 词：O3最大小时浓度 超标率 高压控制 紫外线 

分 类 号：X831[环境科学与工程—环境工程] X16