A new 3-D Gd–Cu heterometallic polymer [Gd_2Cu_3(bpy)_2-(ip)_6]·6H_2O with a non-interpenetrated α-Po net  

作　　者：JIA XiangLi ZHOU Jian ZHAO JunWei LI ZhaoHui ZHENG ShouTian YANG GuoYu 

机构地区：[1]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002, China [2]College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475000, China [3]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

出　　处：《Chinese Science Bulletin》2009年第23期4272-4276,共5页

基　　金：Supported by the National Natural Science Foundation for Distinguished Young Scholars of China (Grant No. 20725101);Major State Basic Research Development Program of China (Grant No. 2006CB932904);Natural Science Foundation of Fujian Province (Grant Nos. E0510030, 2008F3120);National Natural Science Fund of China (Grant Nos. 50872133, 20821061);Knowledge Innovation Program of the CAS (Grant No. KJCX2.YW.H01)

摘　　要：A new 3-D porous Gd-Cu heterometallic polymer [Gd2Cu3(bpy)2(ip)6]·6H2O (1) (bpy = 2,2'-bipyridine, H2ip = isophthalic acid) has been hydrothermally synthesized and structurally characterized. Compound 1 crystallizes in the triclinic space group P1and displays a 3-D non-interpenetrated α-Po network with 1-D channels filled transversely by the hexa-nuclear chain-like (H2O)6. The EPR and thermal stability of 1 were investigated.A new 3-D porous Gd-Cu heterometallic polymer [Gd2Cu3（bpy）2- （ip）6]·6H2O （1） （bpy = 2,2′-bipyridine, H2ip = isophthalic acid） has been hydrothermally synthesized and structurally characterized. Compound 1 crystallizes in the triclinic space group P1and displays a 3-D non-interpenetrated α-Po net- work with 1-D channels filled transversely by the hexa-nuclear chain-like （H2O）6. The EPR and thermal stability of 1 were investigated.

关 键 词：联吡啶 聚合物 IP 铜 钆 水热合成 间苯二甲酸 知识产权 

分 类 号：O614.33[理学—无机化学] TE357.46[理学—化学]