水杨醛缩2-芴胺席夫碱的合成、晶体结构及生物活性  

Synthesis,crystal structure and biological activity of salicylaldehyde-fluoreylamine Schiff base

作　　者：刘红霞[1] 张业明[1] 朱雅兰[1] 刘桥阳[1] 吴风林[1] 

机构地区：[1]黄石理工学院环境科学与工程学院,湖北黄石435003

出　　处：《化学研究与应用》2009年第11期1571-1574,共4页Chemical Research and Application

基　　金：黄石理工学院科研项目(08yjz27B)资助

摘　　要：The synthesis of a new Schiff base(salicylaldehyde-fluorenylamine) with fluorene was reported.The molecular structure was characterized by IR,1H NMR,MS and elementary analysis.The crystal structure was determined by X-ray diffraction method.The crystal belongs to monoclinic,space group P2(1)/c with a =1.60170(6)nm,b=0.82261(8)nm,c=1.11693(2)nm,β=96.671(7)°,V= 1.4617(2) nm3,Z=4,Dc = 1.297g/cm3,μ(MoKα) = 0.080mm-1,F(000) = 600,R1= 0.0857,WR2= 0.1989.The biological activity test indicated that it was an effective bactericide on bacillus such as Staphylococcus aureus,Bacillus thuring Iensis and Bacillus subtilis.The synthesis of a new Schiff base（salicylaldehyde-fluorenylamine） with fluorene was reported.The molecular structure was characterized by IR,1H NMR,MS and elementary analysis.The crystal structure was determined by X-ray diffraction method.The crystal belongs to monoclinic,space group P2（1）/c with a =1.60170（6）nm,b=0.82261（8）nm,c=1.11693（2）nm,β=96.671（7）°,V= 1.4617（2） nm^3,Z=4,Dc= 1.297g/cm^3,μ（MoKα） = 0.080mm^-1,F（000） = 600,R1 = 0.0857,WR2 =0. 1989. The biological activity test indicated that it was an effective bactericide on bacillus such as Staphylococcus aureus, Bacillus thuring lensis and Bacillus subtilis.

关 键 词：水杨醛 2-芴胺 席夫碱 晶体结构 生物活性 

分 类 号：O629.3[理学—有机化学]