氨基硫脲基新型杯[4]芳烃衍生物的合成  

Synthesis of a novel calix[4]arene derivatives containing amino and thiourea

作　　者：蔡秀琴[1] 赵秋伶[1] 王淑荣[1] 

机构地区：[1]渭南师范学院化学化工系,陕西渭南714000

出　　处：《应用化工》2009年第11期1589-1590,共2页Applied Chemical Industry

基　　金：渭南师范学院专项科研基金项目(06YKZ013;06YKZ015)

摘　　要：通过1,3-环氧丙基杯[4]烃与硫代氨基脲开环反应,合成硫代氨基脲基杯[4]芳烃衍生物,研究了其对阳离子的吸附性能后发现,与其他氨基杯芳烃相比,该衍生物对铜离子的吸附性能较好,并且有很好的选择性。A novel calix [ 4 ] arene derivative was synthesized via the ring-opening reaction of 1,3-ep- oxypropyl calix [ 4 ] arene and thiosemicarbazide. After researching the adsorbtion to the cations, it was found that comparing with other amino arenes, the calix[4 ] arene derivative had perfect adsorbtive ability to copper ions and good selectivity.

关 键 词：杯[4]芳烃 环氧氯丙烷 硫代氨基脲 

分 类 号：O625.7[理学—有机化学]