碘作为Lewis酸催化剂在合成中的应用进展  

Progress in Synthetic Application of Iodine as a Lewis Acid Catalyst

作　　者：周颖[1] 闫鹏飞[1] 李光明[1] 陈正军[1] 

机构地区：[1]黑龙江大学化学化工与材料学院功能有机重点实验室,哈尔滨150080

出　　处：《有机化学》2009年第11期1719-1727,共9页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.20672032);黑龙江省教育厅(No.11521205)资助项目

摘　　要：碘催化的有机反应具有价廉易得、操作简单、温和、清洁、高效及高选择性等优点,广泛应用于亲电反应、亲核反应、多组份反应以及其它涉及复杂官能团化合物的合成反应中,在环境友好化学合成、复杂化合物合成及选择性合成领域具有应用价值.The synthestic application of iodine used as a Lewis acid catalyst is reviewed, including electrophilic and nucleophilic reactions, multi-component reactions as well as those for complicated compound synthesis. These iodine-catalyzed reactions are cheap and commercially available and proceeded facilely, mildly, cleanly, in high yields along with high chemo- and regio-selectivities.

关 键 词：碘 LEWIS酸 催化 绿色化学 多组份反应 选择性 

分 类 号：TQ203.2[化学工程—有机化工]