Mechanochemical decomposition of pentachlorophenol by ball milling  

作　　者：WEI Yinglei, YAN Jianhua, LU Shengyong, LI XiaodongState Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China. 

出　　处：《Journal of Environmental Sciences》2009年第12期1761-1768,共8页环境科学学报（英文版）

基　　金：supported by the National Natural Science Foundation of China (No. 50776081);the Doctoral Program of Higher Education (No. 20060335129);the Project on Science and Technology of Zhejiang Province of China (No. 2008C23090)

摘　　要：The mechanochemical dechlorination of pentachlorophenol （PCP） was studied using CaO and SiO2 powder as additives. The effects of the milling time and additives on the dechlorination rate were investigated. The resulting product was characterized by X-ray diffraction （XRD）, Fourier transform infrared spectra （FT-IR）, thermogravimetric analysis （TG） and ion chromatography （IC）. It is found that grinding operation could dechlorinate PCP, with the formation of inorganic chloride and amorphous carbon. The addition of quartz to the grinding mixture facilitated dechlorination. On the basis of the experimental results, the decomposition mechanism was proposed. Decomposition predominantly proceeds through rupture of C-Cl bond in PCP molecule, followed by the formation of inorganic chlorides.The mechanochemical dechlorination of pentachlorophenol （PCP） was studied using CaO and SiO2 powder as additives. The effects of the milling time and additives on the dechlorination rate were investigated. The resulting product was characterized by X-ray diffraction （XRD）, Fourier transform infrared spectra （FT-IR）, thermogravimetric analysis （TG） and ion chromatography （IC）. It is found that grinding operation could dechlorinate PCP, with the formation of inorganic chloride and amorphous carbon. The addition of quartz to the grinding mixture facilitated dechlorination. On the basis of the experimental results, the decomposition mechanism was proposed. Decomposition predominantly proceeds through rupture of C-Cl bond in PCP molecule, followed by the formation of inorganic chlorides.

关 键 词：ball milling DECHLORINATION MECHANOCHEMICAL PENTACHLOROPHENOL 

分 类 号：O621.2[理学—有机化学]