热固性环氧沥青材料的制备及改性方法研究进展  

Advance in preparation and modification methods of thermosetting epoxy asphalt materials

作　　者：黄坤[1] 夏建陵[1,2] 李梅[1] 丁海阳[1] 

机构地区：[1]中国林业科学研究院林产化学工业研究所,江苏南京210042 [2]国家林业局林产化学工程重点开放性实验室,江苏南京210042

出　　处：《热固性树脂》2009年第6期50-54,共5页Thermosetting Resin

基　　金：国家自然科学基金(30771691)

摘　　要：从增强环氧树脂与石油沥青的相容性、改善环氧沥青混合料的适用性和提高环氧沥青的性能3个方面综述了热固性环氧沥青材料的制备方法和改进工艺的研究进展。主要包括马来酸酐改性沥青提高沥青与环氧树脂的相容性;选择与沥青相容性好的固化剂提高环氧-固化剂体系与沥青的相容性;加入增容剂来提高沥青与环氧树脂的相容性。通过选择脂肪羧酸类固化剂并采取加入叔胺或者季铵盐类促进剂的方法调整环氧沥青混合料的固化时间。开发长链低黏度脂肪族羧酸(酐)类固化剂,能够改进环氧沥青材料的综合性能。Advance in preparation and modification methods of thermosetting epoxy asphalt materials, including increasing the compatibility of epoxy resin and asphalt, improving the applicability of epoxy asphalt composites and enhancing the properties of epoxy asphalt was summerized. The compatibility of epoxy resin and asphalt could be improved by using maleic anhydride modified asphalt or ehosing the curing agents with good compatibility to asphalt or adding compatibilizer. The curing time of epoxy asphalt blends could be adjusted by adding fatty acid curing agents and tertiary amine or quaternary ammonium salt as accelerants to the epoxy asphalt composites. The long chain fatty acids or anhydrides with low viscosity could improve the comprehensive properties of epoxy asphalt.

关 键 词：环氧沥青 制备 马来酸酐 增容剂 脂肪族羧酸 固化剂 

分 类 号：TQ323.5[化学工程—合成树脂塑料工业]