卟啉自组装超薄膜的制备及其在光电转换方面的研究  

Fabrication and Photoelectric Conversion Properties of Self-Assembled Functional Films Based on Porphyrins

作　　者：赵玮[1] 佟斌[1] 支俊格[2] 潘月秀[1] 申进波[1] 董宇平[1] 

机构地区：[1]北京理工大学材料科学与工程学院,北京100081 [2]北京理工大学理学院,北京100081

出　　处：《化学进展》2009年第12期2625-2634,共10页Progress in Chemistry

基　　金：国家自然科学基金项目(No.50573008;20634020);教育部博士点专项基金项目(No.20050007018)资助

摘　　要：卟啉及其衍生物的π电子共轭平面结构,使其具有独特的光电性能和良好的热稳定性,在仿生、催化、医学及材料科学等领域得到了广泛的应用。随着自组装技术的不断发展,其在制备功能化超薄膜方面表现出显著的优越性。本文重点介绍了卟啉及其衍生物自组装超薄膜的制备方法,并总结了近年来卟啉自组装膜在光电转换方面的研究进展。Porphyrins exhibit excellent photoelectronic properties and thermal stability due to their special π- electronic system and conjugated delocalized structure, which have been widely used in bionics, catalysis, medicine and materials science. With the progress of self-assembly technology, porphyrins as the building blocks for self-assembled uhrathin films reveal the significant superiority. This review focuses on the fabrication methods of self-assembled functional films based on porphyrins. And the recent progress of porphyrin self-assembled films applied in photoelectric conversion is summarized.

关 键 词：卟啉 自组装超薄膜 光电转换性能 

分 类 号：O625.6[理学—有机化学] O648.22[理学—化学]