含丙基桥联双二茂铁的α,β-不饱和羰基衍生物的合成及电化学性质  

Synthesis and electrochemical behavior of α,β-unsaturated carbonyl compounds bearing propyl-bridged biferrocenyl substituents

作　　者：冯珊[1] 卫兵[2] 李恒东[2] 高勇[2] 袁耀锋[2] 

机构地区：[1]福建卫生职业技术学院,福建福州350101 [2]福州大学化学化工学院,福建福州350108

出　　处：《福州大学学报（自然科学版）》2009年第6期919-923,共5页Journal of Fuzhou University(Natural Science Edition)

基　　金：福建省自然科学基金资助项目(2006J0112)

摘　　要：甲酰基丙基桥联双二茂铁和乙酰基丙基桥联双二茂铁分别与不同的芳香族羰基化合物在氢氧化钠催化下进行Aldol缩合,可简便地得到含丙基桥联双二茂铁的α,β-不饱和羰基衍生物,产率均在86%以上.产物结构经1HNMR,IR及质谱进行了表征.用循环伏安法对标题化合物的电化学性质进行了研究,电化学数据表明该类化合物均呈现出双核甚至多核电化学不等价性特征.Aldol condensation of 1＇ - formyl - 2, 2 - biferrocenylpropane or 1 ＇ - acetyl - 2, 2 - bi- ferrocenylpropane with aromatic compounds containing acetyl or formyl group afforded α,β-unsaturated carbonyl derivatives of propyl -bridged biferrocene in 81% -96% yields by using sodium hydroxide as a catalyst. All of these compounds are determined by MS, IR and ^1HNMR spectra. The electrochemical behavior of title compounds are investigated by the cyclic vohammetry. Electrochemical measurements showed that there are dinuclear even multi - core electrochemical unequivalence in the compounds.

关 键 词：丙基桥联双二茂铁 羟醛缩合 芳香族羰基化合物 电化学 

分 类 号：O627.8[理学—有机化学]