煤基活性炭负载硫酸铈催化合成丙酸丁酯  

Synthesis of butyl propionate catalyzed by cerium sulfate supported on coal based activated carbon

作　　者：马波[1] 王金柱 宋春来[3] 邵景景[3] 

机构地区：[1]大庆油田化工集团东昊公司油气处理分公司,黑龙江大庆163312 [2]焦作职工医学院,河南焦作454000 [3]黑龙江科技学院资源与环境工程学院,黑龙江哈尔滨150027

出　　处：《洁净煤技术》2009年第6期75-77,105,共4页Clean Coal Technology

基　　金：黑龙江教育厅科学技术研究项目(11531328)

摘　　要：为寻求丙酸丁酯的绿色合成方法,以煤基活性炭负载Ce_2(SO_4)_3催化合成丙酸丁酯,用正交实验法,考察醇酸比、催化剂用量和反应时间等3个因素对丙酸丁酯酯化率的影响,获得了最适宜合成条件:醇酸比1.4:1,催化剂用量0.6g,反应时间40min。此时,酯化率可达97%以上。结果表明:煤基活性炭负载Ce_2(SO_4)_3对丙酸丁酯的合成具有较好的催化活性。In order to find a green route of butyl propionate, this paper studied the synthesis of butyl propionate catalyzed by Ce2 （SO4） 3 supported on coal based activated carbon, the factor of esterification reaction yield, such as ratio between alcohol and acid, weight of catalyst and reaction time by the method of orthogonal design. Obtain the best synthesis conditions： the molar ratio of 1.4 ： 1, weight of catalyst of 0.6g, reaction time of 40min, The optimum condition showed the esterifieation reaction yield of over 97%. The results showed that Ce2 （ SO4） 3 supported on coal based activated carbon had a good catalytic activity for the synthesis of butyl propionate.

关 键 词：硫酸铈 丙酸丁酯 煤基活性炭 酯化率 

分 类 号：TQ225.24[化学工程—有机化工]