Syntheses,Structures and Luminescent Property of Two Supramolecular Complexes Containing N-P-Acetamidobenzenesulfonyl-glycine Acid Ligand  

作　　者：王新德 王永伟 尹卫平 王利亚 马录芳 

机构地区：[1]Liming Research Institute of Chemical Industry,China Haohua (Grop) Co. [2]Department of Chemistry,Henan University of Science and Technology [3]College of Chemistry and Chemical Engineering,Luoyang Normal University

出　　处：《Chinese Journal of Structural Chemistry》2009年第12期1645-1651,共7页结构化学（英文）

基　　金：supported by the National Natural Science Foundation of China (Nos. 20771054 and 20471026) ;Henan Tackle Key Problem of Science and Technology (Nos. 072102270030 and 072102270034)

摘　　要：Making use of N-P-acetamidobenzenesulfonyl-glycine acid （abbreviated as abglyH2）,two transitional metal complexes [Zn（abglyH）（phen）2]ClO4·H2O （1） and Co（abglyH）2（bipy）2（H2O）2 （2） （phen = 1,10-phenanthroline,bipy = 4,4＇-bipyridine） have been synthesized under mild conditions and characterized by IR,elemental analysis and X-ray diffraction analysis. Complex 1 is a monomeric compound which is further assembled by intermolecular hydrogen bonds and π-π interaction into a 2-D supramolecular network. Complex 2 is also a monomeric compound and further connected by intermolecular hydrogen bonds to form a 2-D supramolecular network. Fluorescent analysis shows that complex 1 has an emissive maximum at 364 nm in the solution state at room temperature.Making use of N-P-acetamidobenzenesulfonyl-glycine acid （abbreviated as abglyH2）,two transitional metal complexes [Zn（abglyH）（phen）2]ClO4·H2O （1） and Co（abglyH）2（bipy）2（H2O）2 （2） （phen = 1,10-phenanthroline,bipy = 4,4＇-bipyridine） have been synthesized under mild conditions and characterized by IR,elemental analysis and X-ray diffraction analysis. Complex 1 is a monomeric compound which is further assembled by intermolecular hydrogen bonds and π-π interaction into a 2-D supramolecular network. Complex 2 is also a monomeric compound and further connected by intermolecular hydrogen bonds to form a 2-D supramolecular network. Fluorescent analysis shows that complex 1 has an emissive maximum at 364 nm in the solution state at room temperature.

关 键 词：N-P-acetamidobenzenesulfonyl-glycine acid supramolecular structure fluorescent property 

分 类 号：O621.3[理学—有机化学]