从[MoS_4]^(2-)制备一个[MoOS_3]^(2-)型簇合物的低热固相反应机理  

The Mechanism of the Low-heating Soild State Reaction of synthesis one[MoOS_3] type cluster by [MoS_4]^(2-)

作　　者：王荣[1] 孙静静[1] 金琼花[1] 

机构地区：[1]首都师范大学化学系,北京100048

出　　处：《首都师范大学学报（自然科学版）》2009年第6期20-23,共4页Journal of Capital Normal University：Natural Science Edition

摘　　要：首次以含[MoS4]2-离子的(NH4)2MoS4为原料,与Cu(AC)2.H2O和PPh3在空气中研磨使其发生固相反应得到红色的固体.将此固体经CH3CN萃取,放置几天后可得到红黑色单晶[MoCu3OS3(PPh3)3(CH3COO)].测试了其晶体结构,并对该低热固相反应的机理进行了研究.The [MoOS3] type of cluster [MoCu3OS3（PPh3）3（CH3COO）] was first synthesized by the reaction of （NH4）2MoS4 containing [MoS4] 2-ion,PPh3 and Cu（AC）2·H2O in the soild state,and the complex was characterized by IR,X-ray structure determination. The mechanism of this reaction is discussed.

关 键 词：固相合成 晶体结构 Mo-Cu-S簇合物 反应机理 

分 类 号：O614.121[理学—无机化学] O641.4[理学—化学]