纺织品与食品包装材料中烷基酚及双酚A迁移量的液相色谱-串联质谱分析  

Analysis of Alkylphenols and Bisphenol A Migration from Textiles and Food Packaging Materials by Liquid Chromatography Tandem Mass Spectrometry

作　　者：马强[1] 白桦[1] 王超[1] 张庆[1] 席海为[2] 肖海清[1] 董益阳[1] 王宝麟[1] 

机构地区：[1]中国检验检疫科学研究院,北京100123 [2]北京中医药大学中药学院,北京100102

出　　处：《分析测试学报》2009年第12期1415-1418,1423,共5页Journal of Instrumental Analysis

基　　金：国家质量监督检验检疫总局科技计划资助项目(2007IK094)

摘　　要：建立了纺织品与食品包装材料中烷基酚及双酚A迁移量的液相色谱-串联质谱分析方法。纺织品和食品包装材料浸泡液经Supelclean Envi—Carb石墨化碳黑固相萃取柱净化，以Waters XBridgeC．8（150mm×2．1mm，3．5μm）色谱柱分离后，进行LC—MS／MS多反应监测模式下的定性及定量分析。烷基酚和双酚A在纺织品模拟汗液、食品模拟物介质中特定迁移量的定量下限分别为2、4肛g／kg。在低、中、高3个添加水平下，测得纺织品样品的回收率为83％～91％，相对标准偏差为4．1％～9．0％；食品包装材料样品的回收率为82％～94％．相对标准偏差为3．9％-8．7％。A comprehensive analytical method based on liquid chromatography --tandem mass spectrometry has been developed for the determination of alkylphenols and bisphenol A migration from textiles and food packaging materials. The migration of alkylphenols and bisphenol A from textile samples to artificial perspiration was studied by stirring extraction at 60 r/min in a 37 ℃ water bath for 30 min. The food packaging material samples were soaked by four simulants, including water, 3% （by volume） acetic acid, 10% （by volume） ethanol and isooctane using the simulated contact temperature and time. The extract was cleaned up on a Supelclean Envi-Carb solid phase extraction cartridge and separated on a Waters XBridge C18 （ 150 mm × 2. 1 mm, 3.5 μm） column. Qualitative and quantitative analyses of the analytes were （LOQs） for alkylphenols and bisphenol A were 2 μg/kg and 4 μg/kg, respectively. rials at three spiked levels were 83%-91% carried out under MRM mode. The limits of quantitation specific migrations from textiles and food packaging materials The mean recoveries from textiles and food packaging and 82%-94% , respectively, with RSDs of 4. 1%- mate- 9. 0%and 3.9% - 8. 7% , respectively.

关 键 词：纺织品 食品包装材料 迁移量 烷基酚 双酚A 液相色谱-串联质谱 

分 类 号：O657.63[理学—分析化学] O625.31[理学—化学]