以环三膦腈为核的非线性聚磷腈高分子  

Nonlinear Polymers with Cyclotriphosophazene Core

作　　者：邵立东[1] 胡敏奇[1] 翟玲玲[1] 毕韵梅[1] 

机构地区：[1]云南师范大学化学化工学院,昆明650092

出　　处：《化学通报》2010年第1期96-96,共1页Chemistry

摘　　要：综述了近十多年来以环三膦腈为核的非线性聚膦腈高分子的合成、性能及其应用。重点介绍了直接亲核取代法与多官能团引发剂法在合成以环三膦腈为核的星形高分子中的应用,以及发散法与收敛法在合成以环三膦腈为核的树形高分子中的应用。简要阐述了以环三膦腈为核的星形、树形高分子在光电材料、生物医用材料等方面的应用,并展望了以环三膦腈为核的非线性聚膦腈高分子的发展趋势和方向。The development of synthesis, properties and applications of nonlinear polymers with cyelotriphosophazene core were introduced. The synthetic methods of star-shaped and dendritic eyelotriphosophazene polymers including directly nueleophilic substitution, initiation with multiple functional group, divergent and convergent methods were discussed. The applications of star-shaped and dendritic polymers with cyclotriphosophazene core in photoelectric materials, biomaterials etc were briefly introduced and the prospect of nonlinear polymers with cyclotriphosophazene core was anticipated.

关 键 词：环三膦腈 星形高分子 树形高分子 合成 应用 

分 类 号：O634.51[理学—高分子化学] X703.5[理学—化学]