β-(3,4-环氧环己基)乙基三甲氧基硅烷的合成  

Synthesis of β-(3,4-Epoxycyclohexyl)ethyl Trimethoxysilane

作　　者：于菲[1] 张纪云[1] 刘念丽[1] 王致峰[1] 田来进[1] 

机构地区：[1]曲阜师范大学化学与化工学院,山东省曲阜市273165

出　　处：《曲阜师范大学学报（自然科学版）》2010年第1期84-87,共4页Journal of Qufu Normal University(Natural Science)

基　　金：山东省博士后创新项目专项资金(200702021);胶体与界面化学教育部重点实验室资助课题(200707)

摘　　要：用不同配体的Pt配合物催化三甲氧基硅烷(TMOS)与1,2-环氧-4-乙烯基环己烷(EVCX)的硅氢加成反应合成了β-(3,4-环氧环己基)乙基三甲氧基硅烷.通过气质联用仪对反应产物进行分析,确定了主产物的结构.讨论了催化剂用量、反应温度等条件对反应的影响,筛选出了最佳的的反应条件.Pt-C38H34N2P2催化剂用量为40ppm表现出最佳的催化活性,当反应控温在80-90℃之间,β-(3,4-环氧环己基)乙基三甲氧基硅烷的产率可达80%以上.β-（3,4-Epoxycyclohexyl） ethyl trimethoxysilane were synthesized by the platinum complexes catalyzed hydrosilation reaction of trimethoxysilane and 1,2-epoxy-4-vinylcyelohexane. The products were analyzed by means of GC-MS, and the effects of reaction temperature, the kind of catalyst, and the amount of catalyst on the production rate were discussed. The self - made catalyst has higher catalytic activity. Yield of the addition product can reach 80% under the temperature 80-90 ℃.

关 键 词：铂配合物 1 2-环氧4-乙烯基环己烷 三甲氧基硅烷 硅氢加成 

分 类 号：O627.41[理学—有机化学]