三元钴配合物[Co(thy)(phen)(H_2O)_2]的合成、表征及荧光性能研究  

Synthesis,Characterization and Fluorescence Properties of ternary Complex [Co(thy)(Phen)(H_2O)_2]

作　　者：代红梅[1] 刘蕾[1] 朱明昌[1] 刘洪燕[1] 高恩君[1] 

机构地区：[1]沈阳化工学院配位化学实验室,辽宁沈阳110412

出　　处：《当代化工》2009年第6期556-558,共3页Contemporary Chemical Industry

基　　金：辽宁省百千万人基金(No.2008921054)资助项目

摘　　要：用溶液法合成了钴的配合物[Co(thy)(phen)(H2O)2],对它进行了元素分析、红外光谱表征。其中硫代水杨酸和1,10-邻菲啰啉为双齿配位,分别与Co2+形成稳定的六,五元螯合环。并进一步研究了配合物和配体硫代水杨酸的荧光性质。Complex [Co（thy）（phen）（H2O）2] has been synthesized by solution method and characterized by means of elemental analysis and IR spectra. It reveals that cobalt ion double coordinated with sulfur atom and oxygen atom of thy （thiosalicylic acid） and nitrogen atoms of phen （1,10-phenanthroline） which gave rise to stable six and five member ring respectively. The fluorescence property of the title complex and thy has been investigated.

关 键 词：邻菲啰啉 硫代水杨酸 稳定性 

分 类 号：TQ253[化学工程—有机化工]