环己醇与环己酮在疏水性复合电极上的电化学转化  

Electrochemical transformations of cyclohexanol and cyclohexanone on hydrophobic composite electrode

作　　者：黄紫洋[1] 文新宇[1] 李鹏[1] 林雯[1] 

机构地区：[1]福建师范大学化学与材料学院,福建福州350007

出　　处：《现代化工》2010年第1期44-46,48,共4页Modern Chemical Industry

基　　金：福建省教育厅A类面上项目(JA08034)

摘　　要：将自制的2种疏水性复合电极(M-PTFE,M=Ni、Zn)分别应用于环己醇的电化学氧化和环己酮的电化学还原,测定了不同条件下的循环伏安曲线和电极稳定性,结果表明环己醇电化学氧化的转化率达92.5%和环己酮电化学还原的转化率达94.6%。Hydrophobic metal-poly （tetrafluoroethylene）（M-PTFE, M = Ni or Zn） composite electrode is prepared and used for electrochemical oxidation of cyclohexanol and electrochemical reduction of cyclohexanone. The electrochemical characteristics such as cyclic voltammogram and stability are determined under different conditions. The results show that the conversion ratio of electrochemical oxidation of cyclohexanol can be 92.5 %, and the conversion ratio of electrochemical reduction of cvclohexanone, 94.6 %.

关 键 词：PTFE复合电极 环己醇 环己酮 电化学氧化还原 

分 类 号：TQ150.1[化学工程—电化学工业]