Dawson型P-W-V杂多酸的合成方法研究  

Studies on synthesis of vanadium atom substituted series of dawson-type heteropoly acid(W,P)

作　　者：尹彦冰[1] 朱杨青[1] 孙季如[1] 绳秋月 

机构地区：[1]齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔161006

出　　处：《高师理科学刊》2010年第1期68-70,74,共4页Journal of Science of Teachers＇College and University

基　　金：国家自然科学基金资助项目(20671025);齐齐哈尔市科学技术计划项目(GYGG-08002-1)

摘　　要：采用改良的分步处理合成方法,制备了4种Dawson型磷钨钒杂多酸,详细考察了其生成条件,并对其进行红外光谱以及X射线粉末衍射表征.结果表明,4种磷钨钒杂多酸是具有Dawson结构的杂多化合物,经差热热重分析确定了其结晶水的数目.Four novel vanadium atom substituted series of Dawson-type heteropoly acid （W, P ） were prepared respectively by processing step by step. The effect of reaction conditions on the formation of the four heteropolyacids has been studied. Their structures were determined by IR and XRD. The result indicated the four heteropolyacids have Dawson structure. The number of crystal water in the four heteropolyacids was identified respectively by TG analysis.

关 键 词：DAWSON结构 磷钨钒杂多酸 合成 表征 

分 类 号：TQ225[化学工程—有机化工]