Synthesis and Crystal Structure of (1R,2S,3S,4S)-(6-O-Acetyl-1,2-O-isoproplidene-3,5-dideoxy-α-D-glucofuranoso)-1,3,5-trihydro-2,3-oxathiaindene-2,2-dioxide  

作　　者：张磊 魏国华 杜宇国 

机构地区：[1]State Key Laboratory of Environmental Chemistry and Ecotoxicology,Research Center for Eco-environmental Sciences,Chinese Academy of Sciences

出　　处：《Chinese Journal of Structural Chemistry》2010年第1期134-137,共4页结构化学（英文）

基　　金：supported by the National Natural Science Foundation of China (NSFC#30701043)

摘　　要：（1R,2S,3S,4S）-（6-O-Acetyl-1,2-O-isoproplidene-3,5-dideoxy-α-D-glucofuranoso）-1,3,5-trihydro-2,3-oxathiaindene-2,2-dioxide（C11H16O8S,Mr=308.30） was synthesized and structurally characterized by NMR,MS and single-crystal X-ray diffraction.It belongs to the triclinic system,space group P1 with a=7.0836（14）,b=10.832（2）,c=14.895（3）,α=96.01（3）,β=98.85（3）,γ=108.59（3）o,V=1055.8（4）3,Z=3,Dc=1.455g/cm3,F（000）=486,μ=0.264mm-1,the final R=0.0360 and wR=0.0712.It is a tricyclic sultone derivative composed of three five-membered rings.（1R,2S,3S,4S）-（6-O-Acetyl-1,2-O-isoproplidene-3,5-dideoxy-α-D-glucofuranoso）-1,3,5-trihydro-2,3-oxathiaindene-2,2-dioxide（C11H16O8S,Mr=308.30） was synthesized and structurally characterized by NMR,MS and single-crystal X-ray diffraction.It belongs to the triclinic system,space group P1 with a=7.0836（14）,b=10.832（2）,c=14.895（3）,α=96.01（3）,β=98.85（3）,γ=108.59（3）o,V=1055.8（4）3,Z=3,Dc=1.455g/cm3,F（000）=486,μ=0.264mm-1,the final R=0.0360 and wR=0.0712.It is a tricyclic sultone derivative composed of three five-membered rings.

关 键 词：synthesis crystal structure X-ray diffraction sultone 

分 类 号：O621.25[理学—有机化学]