Synthesis and Structure of a New Coordination Polymer Based on Indium and 1,4-Benzenedicarboxylate  

作　　者：林郑忠 陈莲 岳呈阳 江飞龙 洪茂椿 

机构地区：[1]College of Biological Engineering,Jimei University [2]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences

出　　处：《Chinese Journal of Structural Chemistry》2010年第1期142-145,共4页结构化学（英文）

基　　金：supported by 973 Program (2006CB932900);NNSFC (20571074);NSF of Fujian (2007J172)

摘　　要：A new coordination polymer {[In（bdc）（OH）]·4H2O}n（H2bdc=1,4-benzenedi-carboxylic acid） has been synthesized through hydrothermal conditions,and was characterized by X-ray single-crystal diffraction and other measurements.The complex crystallizes in the orthorhombic system,space group Imma with a=18.3621（13）,b=7.1932（5）,c=11.8278（8）,V=1562.24（19）3,Z=4.Dc=1.565g/cm3,Mr=368.00,F（000）=728,μ（MoKα）=1.542 mm–1,S=1.019,R=0.0468 and wR=0.1326 for 884 observed reflections（＆gt;2σ（Ⅰ））.The title compound represents a 3-Dframework containing four kinds of tunnels in different shapes and sizes.A new coordination polymer {[In（bdc）（OH）]·4H2O}n（H2bdc=1,4-benzenedi-carboxylic acid） has been synthesized through hydrothermal conditions,and was characterized by X-ray single-crystal diffraction and other measurements.The complex crystallizes in the orthorhombic system,space group Imma with a=18.3621（13）,b=7.1932（5）,c=11.8278（8）,V=1562.24（19）3,Z=4.Dc=1.565g/cm3,Mr=368.00,F（000）=728,μ（MoKα）=1.542 mm–1,S=1.019,R=0.0468 and wR=0.1326 for 884 observed reflections（＆gt;2σ（Ⅰ））.The title compound represents a 3-Dframework containing four kinds of tunnels in different shapes and sizes.

关 键 词：INDIUM 1 4-benzenedicarboxylate Codc） crystal structure coordination polymer 

分 类 号：O631.3[理学—高分子化学]